Id probably use a couple different sand papers on it. Start with something like a 220 or finer and then get finer as you go in order to get the smoothest finish. As far as paint goes, the one that flexs the most is latex, but most spray paints are oil based. I know that Rustoleum has a paint made specific for plastic that would probably work well or they have one line that is called Painters Touch that is a latex spray paint.
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